A radical new approach in synthetic chemistry

Scientists at the U.S. Department of Energy's (DOE) Brookhaven National Laboratory helped measure how unpaired electrons in atoms at one end of a molecule can drive chemical reactivity on the molecule's opposite side. As described in a paper recently published in the Journal of the American Chemical Society, this work, in collaboration with Princeton University, shows how molecules containing these so-called free radicals could be used in a whole new class of reactions.